Donald Camaioni

(emsl14) Theoretical Characterization of Organic Reaction Intermediates in High Level Wastes

Lead Institution

Pacific Northwest National Laboratory

Principal Investigator

Donald Camaioni

Project type

Capability Research

Computational Design of Catalysts: The Control of Chemical Transformation to Minimize the Environmental Impact of Chemical Processes

Lead Institution

University of Alabama

Principal Investigator

David Dixon

Project type

Capability Research

Catalysis is governed by a delicate balance between a myriad of competing bond making and breaking processes including adsorption, reaction, desorption, and surface diffusion that occur at active…

(emslj3)Elucidation of Mechanisms for Selective Alkane Oxidation

Lead Institution

Pacific Northwest National Laboratory

Principal Investigator

Donald Camaioni

Project type

Capability Research

This proposal will use computational chemistry methods to address questions of how peracids, hydroperoxy-coordinated metal ions and certain ligated metal ions accomplish the conversion of alkanes to…

Experimental and Theoretical Investigations on the
Chemistry and Dynamics of Ammonia Borane Dehydrogenation

Lead Institution

Pacific Northwest National Laboratory

Principal Investigator

Thomas Autrey

Project type

Large-Scale EMSL Research

Increasing demands for clean energy sources that do not add CO2 and other pollutants to the environment have resulted in increased worldwide interest in the possibilities of a "hydrogen economy…

Computational Design of Catalysts: The Control of Chemical Transformation to Minimize the Environmental Impact of Chemical Processes

Lead Institution

University of Alabama

Principal Investigator

David Dixon

Project type

Capability Research

Catalysis is governed by a delicate balance between a myriad of competing bond making and breaking processes including adsorption, reaction, desorption, and surface diffusion that occur at active…

The Reaction Specificity of Nanoparticles in Solution: Interactions between Iron Nanoparticles, their Coatings, and the Environment

Lead Institution

Environmental Molecular Sciences Laboratory

Principal Investigator

Donald Baer

Project type

Large-Scale EMSL Research

The objective of our research is to obtain fundamental information about the physical and chemical transformations that occur on and within mineral oxide nanoparticulates due to electron transfer…

Spectroscopic studies of ambiphilic molecular complexes. Activation of small molecules with non-transition metal catalysis

Lead Institution

Pacific Northwest National Laboratory

Principal Investigator

Thomas Autrey

Project type

Large-Scale EMSL Research

This project will provide fundamental insight into the catalytic activation and transformation of small molecules, e.g., H2, CO2, N2, CH4, by non-metal Lewis pairs in condensed phase environments…

In-situ MAS NMR Investigations on Catalytic Conversion of Biogenic Molecules in the Presence and Absence of Water

Lead Institution

Pacific Northwest National Laboratory

Principal Investigator

Jian-zhi Hu

Project type

Large-Scale EMSL Research

The catalyzed conversion of biomass to hydrocarbon energy carriers requires a cascade of reactions that deconstruct and reduce the polymeric, highly oxofunctionalized biomass material. This chemistry…

Mechanisms and Kinetics of Organic Aging in High-Level Nuclear Waste (PNNL Scope #29531)

Lead Institution

Pacific Northwest National Laboratory

Principal Investigator

Thomas Autrey

Project type

Exploratory Research

Examine the aging of organic chemicals in high-level nuclear wastes stored in tanks at Hanford and develop a mechanistic model describing the reactions and kinetics. The part of the work involving…

Advancing Heterogeneous Catalysis of Routes for the Conversion of Complex Biogenic Feedstocks in Aqueous and Apolar Solvents

Lead Institution

Pacific Northwest National Laboratory

Principal Investigator

Donald Camaioni

Project type

Large-Scale EMSL Research

This proposal aims to provide molecular insight into elementary reaction steps and their kinetics in condensed phases at an atomic and molecular level, which rivals the currently possible insight…

Multinuclear NMR Studies of and Earth and Energy Systems

Lead Institution

Pacific Northwest National Laboratory

Principal Investigator

Karl Mueller

A team of researchers at PNNL carries out studies that utilize high-resolution nuclear magnetic resonance (NMR) spectroscopy in areas of national need for Basic Energy Sciences (BES). The research…

Projects