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(EMSL25) A Computational Investigation of Methane Activation by Transition Metal Complexes with Tris(pyrazolyl)borate and Related Ligation


EMSL Project ID
1846

Abstract

Project Description: Introduction Selective activation of hydrocarbon C-H bonds, particularly those of the lighter alkanes, remains a research topic of considerable interest, because of its relevance to the catalytic conversion of petrochemical feedstocks to more valuable functionalized products. Finding economical catalytic routes to functionalization of methane (the prime component of natural gas) would also be of environmental benefit as it would provide an alternative to flaring, which releases large amounts of greenhouse gases into the environment. For example, the conversion of methane to a more easily transportable liquid (e.g., methanol) would be very attractive.

Project Details

Project type
Capability Research
Start Date
2000-06-09
End Date
2001-10-01
Status
Closed

Team

Principal Investigator

Thomas Cundari
Institution
University of North Texas

Team Members

Stephen Decker
Institution
National Renewable Energy Laboratory

Thomas Klinckman
Institution
University of Memphis