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Understanding of Long-term Phase Stability and Degradations in Solid Oxide Fuel Cells


EMSL Project ID
26712

Abstract

We plan to study the degradation mechanism and phase transitions in solid oxide fuel cells (SOFCs). Specifically, we plan to propose (a) Study of phase separations in SOFC cathode (LSCO) and (LSCF) as a function of various fuel cell exposure conditions including presence of gas phase contaminants. (b) Reduction and reversibility studies of Ni-O in yittria-stabilized zirconia (YSZ) environment as SOFC anode to understand effects of annealing conditions on Ni-O size-distribution and reactivity of Ni catalyst.

Project Details

Project type
Capability Research
Start Date
2007-10-01
End Date
2009-09-30
Status
Closed

Team

Principal Investigator

Prabhakar Singh
Institution
University of Connecticut

Team Members

Lincoln Miara
Institution
Boston University

Nirmal Govindaraju
Institution
University of Cincinnati

Larry Pederson
Institution
Qatar Foundation

David King
Institution
Pacific Northwest National Laboratory

Related Publications

Saraf LV, DR Baer, AS Lea, Z Zhu, JJ Strohm, SD Sitzman, and DL King. 2010. "Bulk Migration of Ni/NiO in Ni-YSZ during Reducing Conditions." Journal of the Electrochemical Society 157(4):B463-B469. doi:10.1149/1.3298442