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Advanced Diagnostic Studies of Lithium Ion Batteries Using In Situ and Ex Situ NMR Spectroscopies


EMSL Project ID
30406

Abstract

Energy shortage is a critical problem in the 21th century. Developing highly efficient and high capacity energy storage device such as lithium iron battery is of considerable interest to the nation. In order to develop next generation of high performance lithium ion battery, a fundamental understanding of the detailed chemical environments and the ion transport mechanisms both inside the electrode and at the interface of electrode-electrolytes is required. This proposed project aims to establish correlations between electrode materials, interfacial phenomena, and cell performance. We propose to apply Pacific Northwest National Laboratorys (PNNL) unique capabilities in high field nuclear magnetic resonance (NMR), including low magnetic fields, to study the formation and evolution of the solid-electrolyte interface (SEI) layer on existing and emerging nanocomposite lithium battery electrodes and the ion transport mechanisms, thereby providing a complement to ongoing diagnostic studies using synchrotron techniques, vibrational spectroscopies, electron microscopy, and magnetic resonance. This project has been funded by PNNL intramural LDRD program started from 10/01/2007 for a period of three years.

Project Details

Project type
Large-Scale EMSL Research
Start Date
2008-08-18
End Date
2011-09-30
Status
Closed

Team

Principal Investigator

Jian-zhi Hu
Institution
Pacific Northwest National Laboratory

Team Members

Kristin Liu
Institution
Pacific Northwest National Laboratory

Bhuvaneswari Sivakumar
Institution
Pacific Northwest National Laboratory

Ju Feng
Institution
Pacific Northwest National Laboratory

Jason Skouson
Institution
Pacific Northwest National Laboratory

Vijayakumar Murugesan
Institution
Pacific Northwest National Laboratory

Jiguang Zhang
Institution
Pacific Northwest National Laboratory

donghai wang
Institution
Pacific Northwest National Laboratory

Daiwon Choi
Institution
Pacific Northwest National Laboratory

Z. Gary Yang
Institution
Pacific Northwest National Laboratory

Jun Liu
Institution
Yale University

Jesse Sears
Institution
Environmental Molecular Sciences Laboratory

Li-Qiong Wang
Institution
Brown University

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Shaw LL, X Wan, JZ Hu, JH Kwak, and Z Yang. 2010. "Solid-State Hydriding Mechanism in the LiBH4 + MgH2 System." Journal of Physical Chemistry C 114(17):8089-8098. doi:10.1021/jp1003837
Vijayakumar M, BM Sivakumar, P Nachimuthu, B Schwenzer, S Kim, Z Yang, J Liu, GL Graff, S Thevuthasan, and JZ Hu. 2011. "Spectroscopic Investigations of the fouling process on Nafion membranes in vanadium redox flow Batteries." Journal of Membrane Science 366(1-2):325-334. doi:10.1016/j.memsci.2010.10.018
Vijayakumar M, B Schwenzer, S Kim, Z Yang, S Thevuthasan, J Liu, GL Graff, and JZ Hu. 2011. "Investigation of Local Environments in Nafion-SiO2 composite membranes used in Vanadium Redox Flow Battery." PNNL-SA-80357, Pacific Northwest National Laboratory, Richland, WA
Vijayakumar M, L Li, GL Graff, J Liu, H Zhang, Z Yang, and JZ Hu. 2011. "Towards understanding the poor thermal stability of V5+ electrolyte solution in Vanadium Redox Flow Batteries." Journal of Power Sources 196(7):3669-3672. doi:10.1016/j.jpowsour.2010.11.126
Vijayakumar M, SD Burton, C Huang, L Li, Z Yang, GL Graff, J Liu, JZ Hu, and M Skyllas-Kazacos. 2010. "Nuclear Magnetic Resonance Studies on Vanadium(IV) Electrolyte Solutions for Vanadium Redox Flow Battery ." Journal of Power Sources 195(22 SP ISS):7709-7717.
Vijayakumar M, SN Kerisit, KM Rosso, SD Burton, JA Sears, Jr, Z Yang, GL Graff, J Liu, and JZ Hu. 2011. "Lithium Diffusion in Li4Ti5O12 at High Temperatures." Journal of Power Sources 196(4):2211-2220.