Gas Phase Study of Solution Phase Species and Chemistry Using Variable Temperature Photoelectron Spectrometer
EMSL Project ID
44678
Abstract
We propose to investigate solution phase species and chemistry in the gas phase using a recently developed low-temperature photoelectron spectrometer. The subjects include but not limited to, temperature-dependent studies on solvation of complex anions, electronic strcuctures of environmentally important diradical species, and dissolution of salts at solution and interfaces.
Project Details
Start Date
2011-10-01
End Date
2014-09-30
Status
Closed
Released Data Link
Team
Principal Investigator
Team Members
Related Publications
Examining the Amine Functionalization in Dicarboxylates: Photoelectron Spectroscopy and Theoretical Studies of Aspartate and Glutamate
Deng S, GL Hou, X Kong, M Valiev, and XB Wang. 2014. "Examining the Amine Functionalization in Dicarboxylates: Photoelectron Spectroscopy and Theoretical Studies of Aspartate and Glutamate." Journal of Physical Chemistry A 118(28):5256-5262. doi:10.1021/jp505439b
The Negative Ion Photoelectron Spectrum of meta-Benzoquinone Radical Anion (MBQ•–): A Joint Experimental and Computational Study
Chen B, D Hrovat, S Deng, J Zhang, XB Wang, and W Borden. 2014. "The Negative Ion Photoelectron Spectrum of meta-Benzoquinone Radical Anion (MBQ•?): A Joint Experimental and Computational Study." Journal of the American Chemical Society 136(9):3589-3596. doi:10.1021/ja412433t
Hydrogen-Bond Networks: Strengths of Different Types of Hydrogen Bonds and An Alternative to the Low Barrier Hydrogen-Bond Proposal
Shokri A, Y Wang, XB Wang, GA O'Doherty, and SR Kass. 2013. "Hydrogen Bond Networks: Strengths of Different Types of Hydrogen Bonds and An Alternative to the Low Barrier Hydrogen Bond Proposal." Journal of the American Chemical Society 135(47):17919-17924. doi:10.1021/ja408762r
Photoelectron spectroscopy and theoretical study of M(IO3)2− (M = H, Li, Na, K): Structural evolution, optical isomers, and hyperhalogen behavior
Hou GL, MM Wu, H Wen, QN Sun, XB Wang, and W Zheng. 2013. "Photoelectron Spectroscopy and Theoretical Study of M(IO3)2– (M = H, Li, Na, K): Structural Evolution, Optical Isomers and Hyperhalogen Behavior." Journal of Chemical Physics 139(4):Article No. 044312. doi:10.1063/1.4816525
Metal-Centered 17-Electron Radicals CpM(CO)3• (M = Cr, Mo, W): A Combined Negative Ion Photoelectron Spectroscopic and Theoretical Study
van der Eide EF, GL Hou, S Deng, H Wen, P Yang, RM Bullock, and XB Wang. 2013. "Metal-Centered 17-Electron Radicals CpM(CO)3• (M = Cr, Mo, W): A Combined Negative Ion Photoelectron Spectroscopic and Theoretical Study." Organometallics 32(7):2084-2091. doi:10.1021/om3011454
Electron-Withdrawing Trifluoromethyl Groups in Combination with Hydrogen Bonds in Polyols: Brønsted Acids, Hydrogen-Bond Catalysts, and Anion Receptors
Shokri A, XB Wang, and SR Kass. 2013. "Electron-Withdrawing Trifluoromethyl Groups in Combination with Hydrogen Bonds in Polyols: Brønsted Acids, Hydrogen-Bond Catalysts, and Anion Receptors." Journal of the American Chemical Society 135(25):9525-9530. doi:10.1021/ja4036384
Three Hydrogen Bond Donor Catalysts: Oxyanion Hole Mimics and Transition State Analogues
Beletskiy EV, JC Schmidt, XB Wang, and SR Kass. 2012. "Three Hydrogen Bond Donor Catalysts: Oxyanion Hole Mimics and Transition State Analogues." Journal of the American Chemical Society 134(45):18534-18537. doi:10.1021/ja3085862
A Combined Gas-Phase Photoelectron Spectroscopic and Theoretical Study of Zeise’s Anion and Its Bromine and Iodine Analogues
Hou G, H Wen, KA Lopata, W Zheng, K Kowalski, N Govind, XB Wang, and SS Xantheas. 2012. "A Combined Gas-Phase Photoelectron Spectroscopic and Theoretical Study of Zeise's Anion and Its Bromine and Iodine Analogues." Angewandte Chemie International Edition 51(26):6356-6360. doi:10.1002/anie.201201959
Probing the Low-Lying Electronic States of Cyclobutanetetraone (C4O4) and Its Radical Anion: A Low-Temperature Anion Photoelectron Spectroscopic Approach
Guo JC, G Hou, SD Li, and XB Wang. 2012. "Probing the Low-lying Electronic States of Cyclobutanetetraone (C4O4) and its Radical Anion: A Low-Temperature Anion Photoelectron Spectroscopic Approach." The Journal of Physical Chemistry Letters 3(3):304-308. doi:10.1021/jz201593z