Interactions between Functionalized Graphene and Electrochemically Active Materials in Advanced Energy Storage System
EMSL Project ID
47414
Abstract
The overall goal of this project is to understand the roles of functionalized graphene in energy storage systems spanning from Li-ion, Li-S to Li-air batteries. Specifically, the morphology of graphene itself along with the functional groups on graphene substrate will be systematically probed and correlated with the final electrochemical performances in different cells. Leveraged with the strong materials synthesis capabilities in PNNL, the proposed work will focus on 1) characterization of manipulated graphene morphology; 2) probe the defects/functional groups on graphene substrate; 3) understand the interactions between functionalized graphene with the reaction products aided by atomic simulations.
Project Details
Project type
Large-Scale EMSL Research
Start Date
2012-10-01
End Date
2014-09-30
Status
Closed
Released Data Link
Team
Principal Investigator
Co-Investigator(s)
Team Members
Related Publications
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Liu TL, Y Shao, G Li, M Gu, JZ Hu, S Xu, Z Nie, X Chen, CM Wang, and J Liu. 2014. "A Facile Approach Using MgCl2 to Formulate High Performance Mg2+ Electrolytes for Rechargeable Mg Batteries." Journal of Materials Chemistry A 2(10):3430 - 3438. doi:10.1039/c3ta14825d
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Meduri P, H Chen, J Xiao, JJ Martinez, TJ Carlson, J Zhang, and Z Deng. 2013. "Tunable Electrochemical Properties of Fluorinated Graphene." Journal of Materials Chemistry 1(27):7866–7869. doi:10.1039/c3ta11710c
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Xiao J, D Mei, X Li, W Xu, D Wang, GL Graff, WD Bennett, Z Nie, LV Saraf, IA Aksay, J Liu, and J Zhang. 2011. "Hierarchically Porous Graphene as a Lithium-Air Battery Electrode." Nano Letters 11(11):5071-5078. doi:10.1021/nl203332e
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Zheng J, D Lu, M Gu, CM Wang, J Zhang, J Liu, and J Xiao. 2013. "How to Make Reproducible Results for Lithium Sulfur Batteries." PNNL-SA-97863, Pacific Northwest National Laboratory, Richland, WA. [Unpublished]
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Zheng J, M Gu, CM Wang, P Zuo, PK Koech, J Zhang, J Liu, and J Xiao. 2013. "Controlled Nucleation and Growth Process of Li2S2/Li2S in Lithium-Sulfur Batteries." Journal of the Electrochemical Society 160(11):A1992-A1996. doi:10.1149/2.032311jes
Zheng J, M Gu, H Chen, P Meduri, MH Engelhard, J Zhang, J Liu, and J Xiao. 2013. "Ionic Liquid-Enhanced Solid State Electrolyte Interface (SEI) for Lithium Sulfur Batteries." Journal of Materials Chemistry A 1(29):8464-8470. doi:10.1039/C3TA11553D
Zheng J, M Gu, MJ Wagner, K Hays, XS Li, P Zuo, CM Wang, J Zhang, J Liu, and J Xiao. 2013. "Revisit Carbon/Sulfur Composite for Li-S Battery." PNNL-SA-96367, Pacific Northwest National Laboratory, Richland, WA.