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EFFECTS OF FIRE INTENSTIY ON THE MOLECULAR STRUCTURES OF DISSOLVED BLACK CARBON


EMSL Project ID
48530

Abstract

The proposed research will use Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) to determine the molecular composition of aromatic carbon-rich dissolved black carbon (DBC). Six samples of DBC extracted from pyrogenic organic matter (PyOM) experienced with different fire intensities will be examined. The FT-ICR MS derived data on the composition of DBC will be used along with data derived from UV/VIS spectroscopy, fluorescence spectroscopy, and disinfection byproduct formation potentials in order to evaluate the drinking water safety and chemical characteristics of dissolved organic matter (DOM) exported from fire-disturbed forested watersheds. The results from FT-ICR MS will provide solid evidence that different types of DBC could be generated from forest fire and the types of aromatic compounds in DBC could be fire temperature dependent. Results will also support a NSF CAREER proposal for a more detailed DBC characterization.

Project Details

Project type
Limited Scope
Start Date
2014-08-01
End Date
2014-09-30
Status
Closed

Team

Principal Investigator

Alex Chow
Institution
The Chinese University of Hong Kong

Team Members

Kristyn Roscioli
Institution
Pacific Northwest National Laboratory