Multinuclear Solid-State NMR Studies of Biological, Environmental, and Energy Systems
EMSL Project ID
49164
Abstract
My research team at EMSL carries out a number of studies that utilize a combination of high-resolution, solid-state nuclear magnetic resonance (NMR) spectroscopy and computational chemistry to address areas of national need. My research projects include scientific explorations in environmental, biological, and energy sciences. Specific Aims for the research to be completed include studies in reactive surface area for catalysis science, catalytically-active sites in zeolites and related materials, development of small volume NMR, NMR studies of the energy materials, chemical shift anisotropy measurements to predict magnetic properties in silicates, and studies of dynamical behavior of hydrocarbons under nanopore confinement.
Project Details
Start Date
2015-10-09
End Date
2018-09-30
Status
Closed
Released Data Link
Team
Principal Investigator
Team Members
Related Publications
Controlled Synthesis of Sulfur-Rich Polymeric Selenium Sulfides as Promising Electrode Materials for Long-Life, High-Rate Lithium Metal Batteries
Dong P., K. Han, J. Lee, X. Zhang, Y. Cha, and M. Song. 2018. "Controlled Synthesis of Sulfur-Rich Polymeric Selenium Sulfides as Promising Electrode Materials for Long-Life, High-Rate Lithium Metal Batteries." ACS Applied Materials & Interfaces 10, no. 35:29565-29573. PNNL-SA-138167. doi:10.1021/acsami.8b09062
25Mg NMR and computational modeling studies of the solvation structures and molecular dynamics in magnesium based liquid electrolytes
Hu J.Z., N. Rajput, C. Wan, Y. Shao, X. Deng, N.R. Jaegers, and M.Y. Hu, et al. 2018. "25Mg NMR and Computational Modeling Studies of the Solvation Structures and Molecular Dynamics in Magnesium Based Liquid Electrolytes." Nano Energy 46. PNNL-SA-130126. doi:10.1016/j.nanoen.2018.01.051
Controlling Solid–Liquid Conversion Reactions for a Highly Reversible Aqueous Zinc–Iodine Battery
Pan H, B Li, D Mei, Z Nie, Y Shao, G Li, XS Li, KS Han, KT Muller, VL Sprenkle, and J Liu. 2017. "Controlling Solid-Liquid Conversion Reactions for Highly Reversible Aqueous Zinc-Iodine Battery." ACS Energy Letters 2:2674–2680. doi:10.1021/acsenergylett.7b00851
Effects of Anion Mobility on Electrochemical Behaviors of Lithium–Sulfur Batteries
Han KS, J Chen, R Cao, NN Rajput, V Murugesan, L Shi, H Pan, J Zhang, J Liu, KA Persson, and KT Mueller. 2017. "Effects of Anion Mobility on Electrochemical Behaviors of Lithium-Sulfur Batteries." Chemistry of Materials 29(21):9023-9029. doi:10.1021/acs.chemmater.7b02105
High-resolution microstrip NMR detectors for subnanoliter samples
Chen Y, HS Mehta, M Butler, ED Walter, PN Reardon, RS Renslow, KT Mueller, and NM Washton. 2017. "High-Resolution Microstrip NMR Detectors for Subnanoliter Samples." Physical Chemistry Chemical Physics. PCCP 19(41):28163-28174. doi:10.1039/c7cp03933f
Toward high-resolution NMR spectroscopy of microscopic liquid samples
Butler M, HS Mehta, Y Chen, PN Reardon, RS Renslow, M Khbeis, D Irish, and KT Mueller. 2017. "Toward high-resolution NMR spectroscopy of microscopic liquid samples." Physical Chemistry Chemical Physics. PCCP 19(22):14256-14261. doi:10.1039/c7cp01933e
Toward the design of high voltage magnesium–lithium hybrid batteries using dual-salt electrolytes
Cheng Y, D Choi, KS Han, KT Mueller, J Zhang, VL Sprenkle, J Liu, and G Li. 2016. "Toward the Design of High Voltage Hybrid Magnesium-Lithium Batteries." Chemical Communications 26(31):5379-5382. doi:10. 1039/C6CC00986G
Restricting the Solubility of Polysulfides in Li-S Batteries Via Electrolyte Salt Selection
Chen J, KS Han, WA Henderson, M Vijayakumar, KC Lau, T Dzwiniel, H Pan, LA Curtiss, J Xiao, KT Mueller, Y Shao, and J Liu. 2016. "Restricting the Solubility of Polysulfides in Li-S Batteries Via Electrolyte Salt Selection ." Advanced Energy Materials 6(11):, doi:10. 1002/aenm. 201600160
Facilitated Ion Transport in Smectic Ordered Ionic Liquid Crystals
Lee JH, KS Han, JS Lee, AS Lee, SK Park, SY Hong, JC Lee, KT Mueller, SM Hong, and CM Koo. 2016. "Facilitated Ion Transport in Smectic Ordered Ionic Liquid Crystals." Advanced Materials. doi:10. 1002/adma. 201602702
Ammonium Additives to Dissolve Lithium Sulfide through Hydrogen Binding for High-Energy Lithium–Sulfur Batteries
Pan H, KS Han, M Vijayakumar, J Xiao, R Cao, J Chen, J Zhang, KT Mueller, Y Shao, and J Liu. 2016. "Ammonium additives to dissolve lithium sulfide through hydrogen binding for high energy lithium-sulfur batteries." ACS Applied Materials & Interfaces. doi:10. 1021/acsami. 6b04158
Reversible aqueous zinc/manganese oxide energy storage from conversion reactions
Pan H, Y Shao, P Yan, Y Cheng, KS Han, Z Nie, CM Wang, J Yang, X Li, P Bhattacharya, KT Mueller, and J Liu. 2016. "Reversible aqueous zinc/manganese oxide energy storage from conversion reactions." Nature Energy. doi:10. 1038/nenergy. 2016. 39
Use of steric encumbrance to develop conjugated nanoporous polymers for metal-free catalytic hydrogenation
Use of Steric Encumbrance to Develop Conjugated Nanoporous Polymers for Metal-free Catalytic Hydrogenation
Chengcheng Tian, Xiang Zhu, Carter Win Abney, Ziqi Tian, De-en Jiang, Kee Sung Han, Nancy Washton and Sheng Dai
Journal Article
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC06372A, Communication