In situ TEM study of branched nanocrystal growth mechanism
EMSL Project ID
49651
Abstract
The long-term goal of this project is to understand the growth of complex crystalline structures by aggregation and oriented attachment (OA) of primary nanoparticles. The formation of materials through this process both leads to branched structures of interest for photovoltaics, energy storage devices and catalysis, and appears to be important in biomineral formation by living organisms, as well as non-biogenic geochemical systems. Recently, we made a major breakthrough in understanding the process of OA by demonstrating the ability to directly observe this process in the iron oxyhydroxide system at lattice resolution in situ [5]. Analysis of OA processes allowed us to produce the first estimate of the force that drives OA and show that electrostatics is the most likely source of OA in this system. Successful application of this capability to branched nanowire structures will lead to a new understanding of the underlying mechanisms and controls on the morphology that promise to significantly advance our ability to utilize branching to create functional materials.The purpose of this project is to now apply in situ TEM to TiO2 and ZnO systems, where the growth is highly anisotropic along different crystallographic directions resulting in tree-like structures which we believe are ones in which we can isolate the key factors controlling nucleation, interaction and oriented attachment (OA) of primary particles, and eventual formation of branched nanowires.
Project Details
Start Date
2016-11-03
End Date
2017-09-30
Status
Closed
Released Data Link
Team
Principal Investigator
Team Members
Related Publications
Li D, H Wang, D Xiao, M Song, BA Legg, and J Chun. 2017. "Investigating the magnitude and source of orientation-dependent interactions between TiO2 crystal surfaces." Nanoscale 9(29):10173-10177. doi:10.1039/C7NR03535G