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Investigating spatiotemporal monitoring of soil organic matter using spectral induced polarization


EMSL Project ID
60683

Abstract

Understanding soil organic matter (SOM) dynamic behavior and interactions is critical in determining regional soil fertility and health. SOM controls crop yields, the diversity of microorganisms used to degrade organic pollutants, pesticide sorption, and organo-mineral complexation which has been linked to carbon stabilization potential in bioactive environments. Field scale methods to study the dynamic spatiotemporal behavior of SOM are limited to collecting field samples and performing laboratory analyses; however, this is labor intensive, particularly when looking at changes over time and also may not capture the effects of soil heterogeneities. Only a few studies have evaluated the geophysical method, spectral induced polarization (SIP) as a non-invasive monitoring alternative. These preliminary studies are promising and show that OM increases the SIP response however, it is postulated that as organo-mineral complexes form, ionic mobility decreases in tandem with the SIP signal. The objective of this proposal is to evaluate SIP as a tool for understanding SOM biogeochemical behavior. Using a staged approach, we propose to 1) evaluate the sensitivity of SIP changes in organo-mineral complexation in microfluidic experiments 2) evaluate this SIP response using relaxation and mechanistic models 3) incorporate this understanding within pore network SIP modeling and 4) move to more complex controlled experiments in laboratory columns with physical and chemical heterogeneity, evaluating proposed models.

Project Details

Start Date
2023-01-26
End Date
2023-10-01
Status
Closed

Team

Principal Investigator

Judith Robinson
Institution
Pacific Northwest National Laboratory

Co-Investigator(s)

Nikolla Qafoku
Institution
Pacific Northwest National Laboratory

Team Members

Frederick Day-Lewis
Institution
Pacific Northwest National Laboratory

Jayde Aufrecht
Institution
Environmental Molecular Sciences Laboratory

Adam Mangel
Institution
Pacific Northwest National Laboratory

Arunima Bhattacharjee
Institution
Environmental Molecular Sciences Laboratory

Thomas Wietsma
Institution
Environmental Molecular Sciences Laboratory