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Influence of Gd and Sm Doping on Atomic and Ionic Transport Properties of Novel Nanostructured Ceria-Zirconia Multilayers


EMSL Project ID
6499

Abstract

This project aims to develop the understanding of ionic transport processes in nanostructured materials that may enable the design of new types of electrolyte materials for electrochemical device applications with enhanced ionic conductivity that function well at low temperatures and establish methods to form such materials as a part of the Nano LDRD program. In this proposed work, we will investigate the fundamental scientific issues associated with atomic and ionic transport properties of multilayer, single- and poly-crystalline nano-oxide film structures on suitable substrates. We will also investigate the role of the electronic structure in nanostructures and atomic and ionic transport of dopants in these nanostructures, along with the thermal, chemical and mechanical stability of these structures. This effort takes advantage of our ability to grow and characterize single-crystal, pure and doped multilayer, nanoscale materials, using state-of-the-art capabilities at the Environmental Molecular Sciences Laboratory (EMSL). We will use the specially constructed multilayered materials to establish a broader scientific understanding of the physical and chemical properties along with the atomic and ionic transport properties of these nanostructures. The ultimate goal is to develop a stable, alternating, multilayer, nano-oxide, thin-film structure that will exhibit significantly higher transport properties at low temperatures. Once this is developed, we will focus our efforts on generating this material system with interfaces normal to the substrate.

Project Details

Project type
Exploratory Research
Start Date
2003-12-11
End Date
2006-12-17
Status
Closed

Team

Principal Investigator

Satyanarayana Kuchibhatla
Institution
Battelle India

Team Members

Lilyann Bauder
Institution
Pacific Northwest National Laboratory

Anthony Cinson
Institution
Pacific Northwest National Laboratory

Yiguang Wang
Institution
Northwestern Polytechnical University

Ponnusamy Nachimuthu
Institution
Environmental Molecular Sciences Laboratory

Sudipta Seal
Institution
University of Central Florida

Vaithiyalingam Shutthanandan
Institution
Environmental Molecular Sciences Laboratory

Chongmin Wang
Institution
Environmental Molecular Sciences Laboratory

Laxmikant Saraf
Institution
Clemson University

Olga Marina
Institution
Pacific Northwest National Laboratory

Zhongqing Yu
Institution
Nanjing Normal University

Theva Thevuthasan
Institution
Environmental Molecular Sciences Laboratory

Anter El-azab
Institution
Purdue University

Dean Matson
Institution
Pacific Northwest National Laboratory

Related Publications

Thevuthasan S, LV Saraf, OA Marina, CM Wang, V Shutthanandan, and PE Burrows. 2009. "Nanoscale Effects on Oxygen Ion Conductance in Oxide Electrolytes." In Handbook of Electrochemical Nanotechnology, ed. YH Lin, HS Nalwa. American Scientific Publishers, Los Angeles, CA.
Thevuthasan S, V Shutthanandan, and Y Zhang. 2006. "Applications of High Energy Ion Beam Techniques in Environmental Science: Investigation Associated with Glass and Ceramic Waste Forms." Journal of Electron Spectroscopy and Related Phenomena 150(2-3):195-207.