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Ultra-Trace Molecular Detection Instrumentation Based on Aerosol Nucleation with Rapid Preconcentration and Separation


EMSL Project ID
9612

Abstract

The threat from the proliferation of nuclear weapons creates a continuous need for the long-term monitoring of chemical signatures of nuclear material production (effluents from uranium conversion and enrichment facilities). Semi-volatile organic chemicals are associated with nuclear processes (e.g. recovery of plutonium for nuclear weapons production, actinide separations) and can provide signatures that will attach to equipment, soil, water and other surface media. Semi-volatile organic chemicals have low but measurable vapor pressure and can be detected in the atmosphere either in the vapor phase or absorbed on particles. Our proposal is based on the extreme sensitivity of the supersaturated vapor in a meta-stable thermodynamic equilibrium near the phase transition gas-liquid (or rather gas - aerosol particle).

Project Details

Project type
Exploratory Research
Start Date
2004-07-15
End Date
2005-12-06
Status
Closed

Team

Principal Investigator

Vladimir Mikheev
Institution
Battelle Columbus

Team Members

Hin-koon Woo
Institution
The Scripps Research Institute

Nels Laulainen
Institution
Pacific Northwest National Laboratory

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