Transient Kinetics Experiments for Studying Catalytic Reactions for H2 Production
EMSL Project ID
16696
Abstract
We will collaborate with Rob Disselkamp to perform transient kinetic analyses (TKA) with isotopic labelling to determine the mechanisms and elementary-step rate constant parameters for catalytic reactions of interest in hydrogen production for use in vehicular fuel cells. We will help develop a state-of-the-art facility for such experiments at EMSL and apply it to such reactions. See attached LDRD proposal for details.
Project Details
Start Date
2005-10-04
End Date
2007-03-22
Status
Closed
Released Data Link
Team
Principal Investigator
Team Members
Related Publications
Simultaneous MS-IR Studies of Surface Formate Reactivity Under Methanol Synthesis Conditions on Cu/SiO2
Yang Y, CA Mims, RS Disselkamp, CHF Peden, and CT Campbell. 2009. "Simultaneous MS-IR Studies of Surface Formate Reactivity Under Methanol Synthesis Conditions on Cu/SiO2." Topics in Catalysis 52(10):1440-1447. doi:10.1007/s11244-009-9320-3
Isotope Effects in Methanol Synthesis and the Reactivity of Copper Formates on a Cu/SiO2 Catalyst
Yang Y, C Mims, RS Disselkamp, D Mei, JH Kwak, J Szanyi, CHF Peden, and CT Campbell. 2008. "Isotope effects in methanol synthesis and the reactivity of copper formates on a Cu/SiO2 catalyst." Catalysis Letters 125(3-4):201-208. doi:10.1007/s10562-008-9592-4