Probing Solution Phase Species and Chemistry Using Variable Temperature Photoelectron Spectrometer
EMSL Project ID
42313
Abstract
We propose to investigate solution phase species and chemistry in the gas phase using a recently developed low-temperature photoelectron spectrometer. The subjects include but not limited to, temperature-dependent studies on solvation of complex anions, electronic structures of environmentally important diradical species, and dissolution of salts at solution and interfaces.
Project Details
Start Date
2010-11-08
End Date
2013-11-24
Status
Closed
Released Data Link
Team
Principal Investigator
Team Members
Related Publications
Fu Q, J Yang, and XB Wang. 2011. "On the Electronic Structures and Electron Affinities of the m- Benzoquinone (BQ) Diradical and the o-, p- BQ Molecules: A Synergetic Photoelectron Spectroscopic and Theoretical Study." Journal of Physical Chemistry A.
Kuvychko IV, JB Whitaker, BW Larson, T Folsom, N Shustova, S Avdoshenko, YS Chen, H Wen, XB Wang, L Dunsch, AA Popov, OV Boltalina, and SH Strauss. 2012. "Substituent Effects In a Series of 1,7-C60(RF)2 Compounds (RF = CF3, C2F5, n-C3F7, i-C3F7, n-C4F9, s-C4F9, n-C8F17): Electron Affinities, Reduction Potentials, and E(LUMO) Values Are Not Always Correlated." Chemical Science 3(5):1399-1407. doi:10.1039/C2SC01133F