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In-Situ/Liquid Time-of-Flight Secondary Ion Mass Spectrometry (TOF-SIMS) for Environmental Interfaces


EMSL Project ID
42330

Abstract

This is a continuation of EMSL project number 36601. A versatile and self-contained interface for high-vapor pressure liquid surfaces, including aqueous interfaces has been built that permits the exploration of the surfaces of these liquids with several vacuum-based analytical instruments. It uses microfluidics to flow the liquid under study past a 3-micron diameter window. This window supports the liquid against the vacuum by the liquids surface tension, while keeping the high-density region traversed by the probe beams to only a few microns. This also limits temperature and concentration changes due to evaporation of the solvent. The beam damage caused by the probe beams is largely negligible, as the flowing liquid surface self-renews. We will in this year extend the method, apply it to new systems and instruments, and publish results.

Project Details

Project type
Exploratory Research
Start Date
2010-12-02
End Date
2011-12-04
Status
Closed

Team

Principal Investigator

James Cowin
Institution
Pacific Northwest National Laboratory

Team Members

Xiao-Ying Yu
Institution
Oak Ridge National Laboratory

Zihua Zhu
Institution
Environmental Molecular Sciences Laboratory

Martin Iedema
Institution
Pacific Northwest National Laboratory

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