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Determination of the Mo...OX bond strengths in oxomolybdenum model complexes.

EMSL Project ID
3686
Award DOI
https://dx.doi.org/10.46936/cpcy.proj.2003.3686/60004384

Abstract

Based on the available data Holm proposed a thermodynamic scale for the propensity of oxygen atom transfer reaction. Under this scheme the feasibility of a substrate to act as an acceptor is judged from the DH of the substrate oxygen bond formation.

Project Details

Start Date
2003-07-18
End Date
2006-07-23
Status
Closed
Released Data Link
https://search.emsl.pnnl.gov/?project_id_search=3686

Team

Principal Investigator

Partha Basu
Institution
Duquesne University

Team Members

Victor Nemykin
Institution
University of Minnesota Duluth

Julia Laskin
Institution
Purdue University

Related Publications

Nemykin VN, J Laskin, and P Basu. 2004. "Isolation, Characterization of an Intermediate in an Oxygen Atom-Transfer Reaction, and the Determination of the Bond Dissociation Energy." Journal of the American Chemical Society 126(28):8604-8605.