Gas Phase Study of Solution Phase Species and Chemistry Using Variable Temperature Photoelectron Spectrometer
EMSL Project ID
51170
Abstract
We propose to investigate solution phase species and chemistry in the gas phase using a recently developed low-temperature photoelectron spectrometer. The subjects include but not limited to, temperature-dependent studies on solvation of complex anions, electronic strcuctures of environmentally important diradical species, and dissolution of salts at solution and interfaces.
Project Details
Start Date
2019-10-08
End Date
2020-09-30
Status
Closed
Released Data Link
Team
Principal Investigator
Team Members
Related Publications
Hou G., and X. Wang. 2020. "Potassium iodide cluster based superhalogens and superalkalis: Theoretical calculations and experimental confirmation." Chemical Physics Letters 741. PNNL-SA-149418. doi:10.1016/j.cplett.2020.137094
Li Z., Y. Jiang, Q. Yuan, J. Warneke, Z. Hu, Y. Yang, and H. Sun, et al. 2020. "Photoelectron spectroscopy and computational investigations of the electronic structures and noncovalent interactions of cyclodextrin-closo-dodecaborate anion complexes x-CD·B12X122- (x = a, ß, y; X = H, F)." Physical Chemistry Chemical Physics. PCCP 22, no. 14:7193-7200. PNNL-SA-151034. doi:10.1039/D0CP00700E
Qin Z., G. Hou, Z. Yang, M. Valiev, and X. Wang. 2020. "Distonic radical anion species in cysteine oxidation processes." Physical Chemistry Chemical Physics. PCCP 22, no. 31:17554-17558. PNNL-SA-152315. doi:10.1039/D0CP02165B
Wang L., Q. Yuan, W. Cao, J. Han, X. Zhou, S. Liu, and X. Wang. 2020. "Probing orientation-specific charge-dipole interactions between hexafluoroisopropanol and halides: A joint photoelectron spectroscopy and theoretical study." Journal of Physical Chemistry A 124, no. 10:2036-2045. PNNL-SA-150323. doi:10.1021/acs.jpca.0c00024
Zhang H., W. Cao, Q. Yuan, X. Zhou, M. Valiev, S.R. Kass, and X. Wang. 2020. "Cryogenic 'Iodide-Tagging' Photoelectron Spectroscopy: A Sensitive Probe for Specific Binding Sites of Amino Acids." Journal of Physical Chemistry Letters 11, no. 11:4346-4352. PNNL-SA-152646. doi:10.1021/acs.jpclett.0c01099
Zhang J., Y. Yang, Z. Sun, and X. Wang. 2020. "Determinants for proton location and electron coupled proton transfer in hydrogen bonded pentafluorophenol-anion clusters." Physical Chemistry Chemical Physics. PCCP 22, no. 29:16712-16720. PNNL-SA-153757. doi:10.1039/D0CP02892D