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Immobilization of radionuclides in the Hanford vadose zone by incorporation in solid phase


EMSL Project ID
2078

Abstract

The objective of the project are: 1. to investigate the effect of aging on the stability of sorption complexes on Al oxyhydroxides surfaces formed from neutralization and homogeneous nucleation of alkaline aluminate solutions; 2. to investigate the sorption/coprecipitation of different contaminants in solids formed from reaction of alkaline aluminate solutions with the Hanford sediments. The XRD analyses that will be conducted at EMSL will help us to determine the components of the newly formed solid phase during dissolution/precipitation processes.

Project Details

Project type
Exploratory Research
Start Date
2000-10-03
End Date
2002-03-31
Status
Closed

Team

Principal Investigator

Nikolla Qafoku
Institution
Pacific Northwest National Laboratory

Related Publications

Effect of Coupled Dissolution and Redox Reactions on Cr(VI)aq Attenuation during Transport in the Sediments under Hyperalkaline Conditions
Qafoku N, CC Ainsworth, JE Szecsody, and O Qafoku. 2003. "Aluminum Effect on Dissolution and Precipitation under Hyperalkaline Conditions: I. Liquid Phase Transformations." Journal of Environmental Quality 32(6):2354-2369.
Qafoku N, CC Ainsworth, JE Szecsody, DL Bish, JS Young, DE McCready, and O Qafoku. 2003. "Aluminum Effect on Dissolution and Precipitation under Hyperalkaline Conditions: II. solid Phase Transformations." Journal of Environmental Quality 32(6):2364-2372.