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Molecular Structure and Interaction at Aqueous, Non-Aqueous Liquid Interfaces and Catalytic Solid Surfaces

EMSL Project ID


With the development of surface nonlinear spectroscopy in the last two decades, it is now possible to interrogate the molecular details of the structure and interactions at molecular interfaces. This project will employ the unique surface nonlinear spectroscopy and dynamics capabilities together with the quantitative methodology in nonlinear spectroscopy and dynamics to investigate important interfacial problems in the energy, environmental, and biological heterogeneous and homogeneous chemical processes. We will investigate aqueous interfaces in order to understand salt and electrolyte effects on the air/water, membrane/water, as well as water/supercritical CO2/mineral interfaces; and electronic structure and charge transport processes of molecules at the air/water, mineral/water interfaces, and in water films. In situ characterization methodology for heterogeneous and homogenous catalysis processes are to be developed and these techniques are to be used to investigate the structure and interactions at the oxide and nanoparticle catalyst surfaces. The following EMSL capabilities are to be employed to condusct this research: Surface nonlinear spectroscopy & dynamics capability (SFG-VS and SHG spectrometers), in addition to other surface & spectroscopic characteriazation capabilities, such as UV-Vis spectroscopy, AFM, etc.

Project Details

Start Date
End Date


Principal Investigator

Hongfei Wang
Fudan University

Team Members

Yunhong Zhang
Beijing Institute of Technology

Related Publications

Feng R, Y Guo, R Lu, LA Velarde Ruiz Esparza, and H Wang. 2011. "Consistency in the Sum Frequency Generation Intensity and Phase Vibrational Spectra of the Air/Neat Water Interface." Journal of Physical Chemistry A 115(23):6015-6027. doi:10.1021/jp110404h
Yu JY, Y Zhang, SH Tan, Y Liu, and Y Zhang. 2012. "Observation on the Ion Association Equilibria in NaNO3 Droplets Using Micro-Raman Spectroscopy." Journal of Physical Chemistry B 116(41):12581–12589. doi:10.1021/jp306367v