Structural and chemical evolutions of advanced energy storage system
EMSL Project ID
50058
Abstract
The objective of the proposed research is to probe the structure-property relationship of next-generation energy materials (such as energy storage materials) under dynamic operating conditions with a range of spatial (down to atomic) and temporal resolution. This goal will be accomplished by using concerted multiscale in-situ spectroscopic and imaging methodologies based on NMR, TEM, STEM, electron energy-loss spectroscopy (EELS), energy-dispersed x-ray spectroscopy (EDS), SEM/FIB, APT, SEM/FIB, XRD, and SIMS. We will in particular probe energy storage materials related to lithium metal and lithium sulfur system.
Project Details
Start Date
2017-10-01
End Date
2020-09-30
Status
Closed
Released Data Link
Team
Principal Investigator
Team Members
Related Publications
Reversible planar gliding and microcracking in a single-crystalline Ni-rich cathode
Bi Y., J. Tao, L. Li, Y. Xu, B. Wu, J. Hu, and C. Wang, et al. 2020. "Direct Observation of Planar Gliding and Cracking in Single Crystalline Ni-rich Cathode for Advanced Li-ion Batteries." Science370, no. 6522:1313-1317. PNNL-SA-152319. doi:10.1126/science.abc3167
Sweeping potential regulated structural and chemical evolution of solid-electrolyte interphase on Cu and Li as revealed by cryo-TEM
Xu Y., H. Wu, H. Jia, M.H. Engelhard, J. Zhang, W. Xu, and C. Wang. 2020. "Sweeping potential regulated structural and chemical evolution of solid-electrolyte interphase on Cu and Li as revealed by cryo-TEM." Nano Energy 76. PNNL-SA-153402. doi:10.1016/j.nanoen.2020.105040
06/24/2020
06/24/2020
Advanced Electrolytes for Fast‐Charging High‐Voltage Lithium‐Ion Batteries in Wide‐Temperature Range
Zhang X., L. Zou, Y. Xu, X. Cao, M.H. Engelhard, B.E. Matthews, and L. Zhong, et al. 2020. "Advanced electrolytes for fast-charging high-voltage lithium-ion batteries in wide-temperature range." Advanced Energy Materials 10, no. 22:2000368. PNNL-SA-150274. doi:10.1002/aenm.202000368
06/09/2020
06/09/2020
Current Density Regulated Atomic to Nanoscale Process on Li Deposition and Solid Electrolyte Interphase Revealed by Cryogenic Transmission Electron Microscopy
Xu Y., H. Wu, H. Jia, J. Zhang, X. Wu, and C. Wang. 2020. "Current density regulated atomic to nanoscale process on Li deposition and solid electrolyte interphase revealed by Cryogenic Transmission Electron Microscopy." ACS Nano 14, no. 7:8766-8775. PNNL-SA-152803. doi:10.1021/acsnano.0c03344
High temperature shockwave stabilized single atoms
Yao Y., Z. Huang, P. Xie, L. Wu, L. Ma, T. Li, and Y. He, et al. 2019. "High Temperature Shockwave Stabilized Single Atoms." Nature Nanotechnology 14, no. 9:851-857. PNNL-SA-143543. doi:10.1038/s41565-019-0518-7
Ni/Li Disordering in Layered Transition Metal Oxide: Electrochemical Impact, Origin, and Control
Zheng J., Y. Ye, T. Liu, Y. Xiao, C. Wang, F. Wang, and F. Pan. 2019. "Ni/Li Disordering in Layered Transition Metal Oxide: Electrochemical Impact, Origin, and Control." Accounts of Chemical Research 52, no. 8:2201-2209. PNNL-SA-140607. doi:10.1021/acs.accounts.9b00033
A high-performance oxygen evolution catalyst in neutral-pH for sunlight-driven CO2 reduction
Zhou L., C. Ling, H. Zhou, X. Wang, J. Liao, G.K. Reddy, and L. Deng, et al. 2019. "A High-performance Oxygen Evolution Catalyst in Neutral-pH for Sunlight-driven CO2 Reduction." Nature Communications 10, no. 2019:4081. PNNL-SA-146421. doi:10.1038/s41467-019-12009-8
The Role of Secondary Particle Structures in Surface Phase Transitions of Ni-Rich Cathodes
Zou L., W. Zhao, H. Jia, J. Zheng, L. Li, D. Abraham, and G. Chen, et al. 2020. "The Role of Secondary Particle Structures in Surface Phase Transitions of Ni-Rich Cathodes." Chemistry of Materials 32, no. 7:2884-2892. PNNL-SA-149781. doi:10.1021/acs.chemmater.9b04938
High‐Power Lithium Metal Batteries Enabled by High‐Concentration Acetonitrile‐Based Electrolytes with Vinylene Carbonate Additive
Peng Z., X. Cao, P. Gao, H. Jia, X. Ren, S. Roy, and Z. Li, et al. 2020. "High-Power Lithium Metal Batteries Enabled by High-Concentration Acetonitrile-Based Electrolytes with Vinylene Carbonate Additive." Advanced Functional Materials 30, no. 24:2001285. PNNL-SA-149736. doi:10.1002/adfm.202001285
Unstable twin in body-centered cubic tungsten nanocrystals
Wang X., J. Wang, Y. He, C. Wang, L. Zhong, and S.X. Mao. 2020. "Unstable twin in body-centered cubic tungsten nanocrystals." Nature Communications 11. PNNL-SA-152500. doi:10.1038/s41467-020-16349-8
Unlocking the passivation nature of the cathode–air interfacial reactions in lithium ion batteries
Zou L., Y. He, Z. Liu, H. Jia, J. Zhu, J. Zheng, and G. Wang, et al. 2020. "Unlocking the passivation nature of the cathode-air interfacial reaction in lithium ion batteries." Nature Communications 11, no. 2020:3204. PNNL-SA-152810. doi:10.1038/s41467-020-17050-6
Hidden Subsurface Reconstruction and Its Atomic Origins in Layered Oxide Cathodes
Li L., E.C. Self, D. Darbar, L. Zou, I. Bhattacharya, D. Wang, and J. Nanda, et al. 2020. "Hidden Subsurface Reconstruction and its Atomic Origins in Layered Oxide Cathodes." Nano Letters 20, no. 4:2756-2762. PNNL-SA-150764. doi:10.1021/acs.nanolett.0c00380
Direct observation of dual-step twinning nucleation in hexagonal close-packed crystals
He Y., B. Li, C. Wang, and S.X. Mao. 2020. "Direct Observation of Dual-Step Twinning Nucleation in Hexagonal Close-Packed Crystals." Nature Communications 11, no. 1:2483. PNNL-SA-152795. doi:10.1038/s41467-020-16351-0
Deciphering atomistic mechanisms of the gas-solid interfacial reaction during alloy oxidation
Luo L., L. Li, D.K. Schreiber, Y. He, D.R. Baer, S.M. Bruemmer, and C. Wang. 2020. "Deciphering atomistic mechanisms of the gas-solid interfacial reaction during alloy oxidation." Science Advances 6, no. 7:Article No. eaay8491. PNNL-SA-147915. doi:10.1126/sciadv.aay8491
Dynamic Atom Clusters on AuCu Nanoparticle Surface during CO Oxidation
Luo L., S. Chen, Q. Xu, Y. He, Z. Dong, L. Zhang, and J. Zhu, et al. 2020. "Dynamic Atom Clusters on AuCu Nanoparticle Surface During CO Oxidation." Journal of the American Chemical Society 142, no. 8:4022-4027. PNNL-SA-150963. doi:10.1021/jacs.9b13901
Lignin‐derived electrochemical energy materials and systems
Wu X., J. Jiang, C. Wang, J. Liu, Y. Pu, A.J. Ragauskas, and S. Li, et al. 2020. "Lignin-Derived Electrochemical Energy Materials and Systems." Biofpr: Biofules, Bioproducts & Biorefining. PNNL-SA-144600. doi:10.1002/bbb.2083
Atomic to Nanoscale Origin of Vinylene Carbonate Enhanced Cycling Stability of Lithium Metal Anode Revealed by Cryo-Transmission Electron Microscopy
Xu Y., H. Wu, Y. He, Q. Chen, J. Zhang, W. Xu, and C. Wang. 2020. "Atomic to Nanoscale Origin of Vinylene Carbonate Enhanced Cycling Stability of Lithium Metal Anode Revealed by Cryo-Transmission Electron Microscopy." Nano Letters 20, no. 1:418-425. PNNL-SA-149594. doi:10.1021/acs.nanolett.9b04111
Nonflammable Electrolytes for Lithium Ion Batteries Enabled by Ultraconformal Passivation Interphases
Cao X., Y. Xu, L. Zhang, M.H. Engelhard, L. Zhong, X. Ren, and H. Jia, et al. 2019. "Nonflammable Electrolytes for Lithium Ion Batteries Enabled by Ultraconformal Passivation Interphases." ACS Energy Letters 4, no. 10:2529-2534. PNNL-SA-145269. doi:10.1021/acsenergylett.9b01926
Electrolyte design for LiF-rich solid–electrolyte interfaces to enable high-performance microsized alloy anodes for batteries
Chen J., X. Fan, Q. Li, H. Yang, M.R. Khoshi, Y. Xu, and S. Hwang, et al. 2020. "Electrolyte Design for LiF-rich Solid-Electrolyte Interfaces to Enable High-performance Microsized Alloy Anodes for Batteries." Nature Energy 5, no. 5:386-397. PNNL-SA-151702. doi:10.1038/s41560-020-0601-1
Atomic-Scale Mechanisms of Enhanced Electrochemical Properties of Mo-Doped Co-Free Layered Oxide Cathodes for Lithium-Ion Batteries
Li L., J. Yu, D. Darbar, E.C. Self, D. Wang, J. Nanda, and I. Bhattacharya, et al. 2019. "Atomic-scale Mechanisms of Enhanced Electrochemical Properties of Mo-doped Co-free Layered Oxide Cathodes for Lithium-Ion Batteries." ACS Energy Letters 4, no. 10:2540-2546. PNNL-SA-146763. doi:10.1021/acsenergylett.9b01830
Origin of lithium whisker formation and growth under stress
He Y., X. Ren, Y. Xu, M.H. Engelhard, X. Li, J. Xiao, and J. Liu, et al. 2019. "Origin of Lithium Whisker Formation and Growth under Stress." Nature Nanotechnology 14, no. 11:1042-1047. PNNL-SA-144887. doi:10.1038/s41565-019-0558-z
Redox Behaviors in a Li-Excess Cation-Disordered Mn–Nb–O–F Rocksalt Cathode
Yue Y., N. Li, L. Li, E. Foley, Y. Fu, V.S. Battaglia, and R. Clement, et al. 2020. "Redox Behaviors in Li-Excess Cation-Disordered Mn-Nb-O-F Rocksalt Cathode." Chemistry of Materials 32, no. 11:4490-4498. PNNL-SA-152425. doi:10.1021/acs.chemmater.9b05221
Polymer‐in‐“Quasi‐Ionic Liquid” Electrolytes for High‐Voltage Lithium Metal Batteries
Wu H., Y. Xu, X. Ren, B. Liu, M.H. Engelhard, M.S. Ding, and P.Z. El-Khoury, et al. 2019. "Polymer-in-"quasi-ionic liquid" electrolytes for high-voltage lithium metal batteries." Advanced Energy Materials 9, no. 41:1902108. PNNL-SA-144443. doi:10.1002/aenm.201902108
Lattice doping regulated interfacial reactions in cathode for enhanced cycling stability
Zou L., J. Li, Z. Liu, G. Wang, A. Manthiram, and C. Wang. 2019. "Lattice Doping Regulated Interfacial Reactions In Cathode For enhanced cycling stability." Nature Communications 10. PNNL-SA-144976. doi:10.1038/s41467-019-11299-2
Injection of oxygen vacancies in the bulk lattice of layered cathodes
Yan P., J. Zheng, Z. Tang, A. Devaraj, G. Chen, K. Amine, and J. Zhang, et al. 2019. "Injection of oxygen vacancies in the bulk lattice of layered cathodes." Nature Nanotechnology 14, no. 6:602-609. PNNL-SA-141286. doi:10.1038/s41565-019-0428-8
Infinitesimal sulfur fusion yields quasi-metallic bulk silicon for stable and fast energy storage
Ryu J., J. Seo, G. Song, K. Choi, D. Hong, C. Wang, and H. Lee, et al. 2019. "Infinitesimal Sulfur Fusion Yields Quasi-Metallic Bulk Silicon for Stable and Fast Energy Storage." Nature Communications 10, no. 1:Article number 2351. PNNL-SA-144155. doi:10.1038/s41467-019-10289-8
Atomic-scale combination of germanium-zinc nanofibers for structural and electrochemical evolution
Song G., J. Cheong, C. Kim, L. Luo, C. Hwang, S. Choi, and J. Ryu, et al. 2019. "Atomic-scale combination of germanium-zinc nanofibers for structural and electrochemical evolution." Nature Communications 10, no. 1:Article No. 2364. PNNL-SA-135597. doi:10.1038/s41467-019-10305-x
High-quality mesoporous graphene particles as high-energy and fast-charging anodes for lithium-ion batteries
Mo R., F. Li, X. Tan, P. Xu, R. Tao, G. Shen, and X. Lu, et al. 2019. "High-quality Mesoporous Graphene Particles as High-energy and Fast-charging Anodes for Lithium-ion Batteries." Nature Communications 10, no. 1:1474. PNNL-SA-143544. doi:10.1038/s41467-019-09274-y
Nonhierarchical Heterostructured Fe2 O3 /Mn2 O3 Porous Hollow Spheres for Enhanced Lithium Storage
Ren W., D. Liu, C. Sun, X. Yao, J. Tan, C. Wang, and K. Zhao, et al. 2018. "Nonhierarchical Heterostructured Fe2O3/Mn2O3 Porous Hollow Spheres for Enhanced Lithium Storage." Small 14, no. 26:1800659. PNNL-SA-135599. doi:10.1002/smll.201800659