Structural and chemical evolutions of advanced energy storage system
EMSL Project ID
50058
Abstract
The objective of the proposed research is to probe the structure-property relationship of next-generation energy materials (such as energy storage materials) under dynamic operating conditions with a range of spatial (down to atomic) and temporal resolution. This goal will be accomplished by using concerted multiscale in-situ spectroscopic and imaging methodologies based on NMR, TEM, STEM, electron energy-loss spectroscopy (EELS), energy-dispersed x-ray spectroscopy (EDS), SEM/FIB, APT, SEM/FIB, XRD, and SIMS. We will in particular probe energy storage materials related to lithium metal and lithium sulfur system.
Project Details
Start Date
2017-10-01
End Date
2020-09-30
Status
Closed
Released Data Link
Team
Principal Investigator
Team Members
Related Publications
Bi Y., J. Tao, L. Li, Y. Xu, B. Wu, J. Hu, and C. Wang, et al. 2020. "Direct Observation of Planar Gliding and Cracking in Single Crystalline Ni-rich Cathode for Advanced Li-ion Batteries." Science370, no. 6522:1313-1317. PNNL-SA-152319. doi:10.1126/science.abc3167
Cao X., Y. Xu, L. Zhang, M.H. Engelhard, L. Zhong, X. Ren, and H. Jia, et al. 2019. "Nonflammable Electrolytes for Lithium Ion Batteries Enabled by Ultraconformal Passivation Interphases." ACS Energy Letters 4, no. 10:2529-2534. PNNL-SA-145269. doi:10.1021/acsenergylett.9b01926
Chen J., X. Fan, Q. Li, H. Yang, M.R. Khoshi, Y. Xu, and S. Hwang, et al. 2020. "Electrolyte Design for LiF-rich Solid-Electrolyte Interfaces to Enable High-performance Microsized Alloy Anodes for Batteries." Nature Energy 5, no. 5:386-397. PNNL-SA-151702. doi:10.1038/s41560-020-0601-1
He Y., B. Li, C. Wang, and S.X. Mao. 2020. "Direct Observation of Dual-Step Twinning Nucleation in Hexagonal Close-Packed Crystals." Nature Communications 11, no. 1:2483. PNNL-SA-152795. doi:10.1038/s41467-020-16351-0
He Y., X. Ren, Y. Xu, M.H. Engelhard, X. Li, J. Xiao, and J. Liu, et al. 2019. "Origin of Lithium Whisker Formation and Growth under Stress." Nature Nanotechnology 14, no. 11:1042-1047. PNNL-SA-144887. doi:10.1038/s41565-019-0558-z
Jin Y., Y. Xu, P. Le, T.D. Vo, M.H. Engelhard, B.E. Matthews, and H. Jia, et al. 2020. "Highly Reversible Sodium Ion Batteries Enabled by Stable Electrolyte-Electrode Interphases." ACS Energy Letters 5, no. 10: 3212-3220. PNNL-SA-153228. doi.org/10.1021/acsenergylett.0c01712
Li L., E.C. Self, D. Darbar, L. Zou, I. Bhattacharya, D. Wang, and J. Nanda, et al. 2020. "Hidden Subsurface Reconstruction and its Atomic Origins in Layered Oxide Cathodes." Nano Letters 20, no. 4:2756-2762. PNNL-SA-150764. doi:10.1021/acs.nanolett.0c00380
Li L., J. Yu, D. Darbar, E.C. Self, D. Wang, J. Nanda, and I. Bhattacharya, et al. 2019. "Atomic-scale Mechanisms of Enhanced Electrochemical Properties of Mo-doped Co-free Layered Oxide Cathodes for Lithium-Ion Batteries." ACS Energy Letters 4, no. 10:2540-2546. PNNL-SA-146763. doi:10.1021/acsenergylett.9b01830
Luo L., L. Li, D.K. Schreiber, Y. He, D.R. Baer, S.M. Bruemmer, and C. Wang. 2020. "Deciphering atomistic mechanisms of the gas-solid interfacial reaction during alloy oxidation." Science Advances 6, no. 7:Article No. eaay8491. PNNL-SA-147915. doi:10.1126/sciadv.aay8491
Luo L., S. Chen, Q. Xu, Y. He, Z. Dong, L. Zhang, and J. Zhu, et al. 2020. "Dynamic Atom Clusters on AuCu Nanoparticle Surface During CO Oxidation." Journal of the American Chemical Society 142, no. 8:4022-4027. PNNL-SA-150963. doi:10.1021/jacs.9b13901
Mo R., F. Li, X. Tan, P. Xu, R. Tao, G. Shen, and X. Lu, et al. 2019. "High-quality Mesoporous Graphene Particles as High-energy and Fast-charging Anodes for Lithium-ion Batteries." Nature Communications 10, no. 1:1474. PNNL-SA-143544. doi:10.1038/s41467-019-09274-y
Peng Z., X. Cao, P. Gao, H. Jia, X. Ren, S. Roy, and Z. Li, et al. 2020. "High-Power Lithium Metal Batteries Enabled by High-Concentration Acetonitrile-Based Electrolytes with Vinylene Carbonate Additive." Advanced Functional Materials 30, no. 24:2001285. PNNL-SA-149736. doi:10.1002/adfm.202001285
Ren W., D. Liu, C. Sun, X. Yao, J. Tan, C. Wang, and K. Zhao, et al. 2018. "Nonhierarchical Heterostructured Fe2O3/Mn2O3 Porous Hollow Spheres for Enhanced Lithium Storage." Small 14, no. 26:1800659. PNNL-SA-135599. doi:10.1002/smll.201800659
Ryu J., J. Seo, G. Song, K. Choi, D. Hong, C. Wang, and H. Lee, et al. 2019. "Infinitesimal Sulfur Fusion Yields Quasi-Metallic Bulk Silicon for Stable and Fast Energy Storage." Nature Communications 10, no. 1:Article number 2351. PNNL-SA-144155. doi:10.1038/s41467-019-10289-8
Song G., J. Cheong, C. Kim, L. Luo, C. Hwang, S. Choi, and J. Ryu, et al. 2019. "Atomic-scale combination of germanium-zinc nanofibers for structural and electrochemical evolution." Nature Communications 10, no. 1:Article No. 2364. PNNL-SA-135597. doi:10.1038/s41467-019-10305-x
Wang X., J. Wang, Y. He, C. Wang, L. Zhong, and S.X. Mao. 2020. "Unstable twin in body-centered cubic tungsten nanocrystals." Nature Communications 11. PNNL-SA-152500. doi:10.1038/s41467-020-16349-8
Wu H., Y. Xu, X. Ren, B. Liu, M.H. Engelhard, M.S. Ding, and P.Z. El-Khoury, et al. 2019. "Polymer-in-"quasi-ionic liquid" electrolytes for high-voltage lithium metal batteries." Advanced Energy Materials 9, no. 41:1902108. PNNL-SA-144443. doi:10.1002/aenm.201902108
Wu X., J. Jiang, C. Wang, J. Liu, Y. Pu, A.J. Ragauskas, and S. Li, et al. 2020. "Lignin-Derived Electrochemical Energy Materials and Systems." Biofpr: Biofules, Bioproducts & Biorefining. PNNL-SA-144600. doi:10.1002/bbb.2083
Xu Y., H. Wu, H. Jia, J. Zhang, X. Wu, and C. Wang. 2020. "Current density regulated atomic to nanoscale process on Li deposition and solid electrolyte interphase revealed by Cryogenic Transmission Electron Microscopy." ACS Nano 14, no. 7:8766-8775. PNNL-SA-152803. doi:10.1021/acsnano.0c03344
Xu Y., H. Wu, H. Jia, M.H. Engelhard, J. Zhang, W. Xu, and C. Wang. 2020. "Sweeping potential regulated structural and chemical evolution of solid-electrolyte interphase on Cu and Li as revealed by cryo-TEM." Nano Energy 76. PNNL-SA-153402. doi:10.1016/j.nanoen.2020.105040
06/24/2020
Xu Y., H. Wu, Y. He, Q. Chen, J. Zhang, W. Xu, and C. Wang. 2020. "Atomic to Nanoscale Origin of Vinylene Carbonate Enhanced Cycling Stability of Lithium Metal Anode Revealed by Cryo-Transmission Electron Microscopy." Nano Letters 20, no. 1:418-425. PNNL-SA-149594. doi:10.1021/acs.nanolett.9b04111
Yan P., J. Zheng, Z. Tang, A. Devaraj, G. Chen, K. Amine, and J. Zhang, et al. 2019. "Injection of oxygen vacancies in the bulk lattice of layered cathodes." Nature Nanotechnology 14, no. 6:602-609. PNNL-SA-141286. doi:10.1038/s41565-019-0428-8
Yao Y., Z. Huang, P. Xie, L. Wu, L. Ma, T. Li, and Y. He, et al. 2019. "High Temperature Shockwave Stabilized Single Atoms." Nature Nanotechnology 14, no. 9:851-857. PNNL-SA-143543. doi:10.1038/s41565-019-0518-7
Yue Y., N. Li, L. Li, E. Foley, Y. Fu, V.S. Battaglia, and R. Clement, et al. 2020. "Redox Behaviors in Li-Excess Cation-Disordered Mn-Nb-O-F Rocksalt Cathode." Chemistry of Materials 32, no. 11:4490-4498. PNNL-SA-152425. doi:10.1021/acs.chemmater.9b05221
Zhang X., L. Zou, Y. Xu, X. Cao, M.H. Engelhard, B.E. Matthews, and L. Zhong, et al. 2020. "Advanced electrolytes for fast-charging high-voltage lithium-ion batteries in wide-temperature range." Advanced Energy Materials 10, no. 22:2000368. PNNL-SA-150274. doi:10.1002/aenm.202000368
06/09/2020
Zheng J., Y. Ye, T. Liu, Y. Xiao, C. Wang, F. Wang, and F. Pan. 2019. "Ni/Li Disordering in Layered Transition Metal Oxide: Electrochemical Impact, Origin, and Control." Accounts of Chemical Research 52, no. 8:2201-2209. PNNL-SA-140607. doi:10.1021/acs.accounts.9b00033
Zhou L., C. Ling, H. Zhou, X. Wang, J. Liao, G.K. Reddy, and L. Deng, et al. 2019. "A High-performance Oxygen Evolution Catalyst in Neutral-pH for Sunlight-driven CO2 Reduction." Nature Communications 10, no. 2019:4081. PNNL-SA-146421. doi:10.1038/s41467-019-12009-8
Zou L., J. Li, Z. Liu, G. Wang, A. Manthiram, and C. Wang. 2019. "Lattice Doping Regulated Interfacial Reactions In Cathode For enhanced cycling stability." Nature Communications 10. PNNL-SA-144976. doi:10.1038/s41467-019-11299-2
Zou L., W. Zhao, H. Jia, J. Zheng, L. Li, D. Abraham, and G. Chen, et al. 2020. "The Role of Secondary Particle Structures in Surface Phase Transitions of Ni-Rich Cathodes." Chemistry of Materials 32, no. 7:2884-2892. PNNL-SA-149781. doi:10.1021/acs.chemmater.9b04938
Zou L., Y. He, Z. Liu, H. Jia, J. Zhu, J. Zheng, and G. Wang, et al. 2020. "Unlocking the passivation nature of the cathode-air interfacial reaction in lithium ion batteries." Nature Communications 11, no. 2020:3204. PNNL-SA-152810. doi:10.1038/s41467-020-17050-6